バイオセラミックスの開発と応用

Variable-Temperature Measurements of the Dielectric Relaxation Spectroscopy in 0.1 SiO2-0.2 Cao-0.2 Na2O-0.5 P2O5 Bioactive Glass Materials

Abstract

Hogga Z, Merzouk N, Hafid MM

Bioactive glasses with chemical composition 0.1 SiO2-0.2 CaO-0.2 Na2O-0.5 P2O5 have been prepared. The dielectric properties of the samples were measured in the frequency range from 100 Hz to 1 MHz and temperatures range from 100 to 370 K (Tg ≈ 400 K). The obtained data were analysed by the means of dielectric permittivity representation and modelled using the Havriliak–Negami equation. Various relaxation parameters were calculated with accuracy. Furthermore, investigation of the temperature dependence of their relaxation time using the Vogel– Tammam–Fulcher (VTF) model shows the weak interaction between alkali ions constituents and molecular networkformers for temperatures up to the glass transition.